1) Kelly Brook. I read an interview with her grandmother years ago, which said that she had "terrible trouble with her teeth", and "wore braces for years". Apparently she was wearing lingual braces when she started presenting "The Big Breakfast"
2) Zara Phillips, of the British royal family. I saw a picture of her in a magazine years ago - she was young and wearing what looked like a retainer but was probably an active plate. Obviously didn't wear her retainer, as her inscisors are badly tilted in now! Maybe she'll get braces again...
3) Cerys Matthews from the band Catatonia - a few (4?) years ago she presented some music programme with another female presenter, and had clearly visible metal lower braces.
4) Kirsten O'Brien - BBC children's tv presenter, wore clear braces and elastics for a while when presenting a kid's art programme. She must have had them taken off early though, because her teeth were awful before, but still very far from perfect!